En Block Approach of Structure Elucidation of Linear Isomeric Aldohexoses as Related to Aldaric (Saccharic) Acids: An Advance Study

The elucidation of the structure of the 16 isomeric linear aldohexoses is approached block by block in a clear, logical, concise, and coherent manner. The main premise, or paradigm, of this paper is Bijvoet’s structure elucidation of (+)-tartaric acid. The other premise is a preparatory method developed by Baer and Fischer, the instructive potential of which is revealed for the first time in this paper. It is about elucidating the configuration of C-2 using di-O-isopropylidenic hexitol derivatives. Furthermore, the entire set of experimental methods developed and used by E. Fischer in the structure elucidation of monosaccharides is available in this chapter.

Author (S) Details

Dumitru Petru I. Iga
University of Bucharest, former C. I. Parhon, Bucharest, Rumania and University of Oradea, B-dul Armata Romana, Oradea, Nagyvárad, Rumania.

Dumitru Popescu
Gh. Mihoc-Caius Iacob Institute of Mathematical Statistics and Applied Mathematics of Romania Academy, 13 Calea 13 Septembrie, 050711, Bucharest, Romania.

Mr. Valentin I. R. Niculescu
Institut de Recherche et Development pour les Lasers, Plasma et Physique de la Radiation, Magurele-Bucharest, Rumania.

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